Oxygen Gas and UV Barrier Properties of Nano-ZnO-Coated PET and PHBHHx Materials Fabricated by Ultrasonic Spray-Coating Technique

Abstract

Ultrasonic spray-coating (USSC)-a wet chemical deposition method to deposit ultrathin (down to 20 nm) coatings-is being applied as a promising alternative deposition method for functional coatings due to an economical, simple, and precise coating process with easy control over its operating parameters. In this research, zinc oxide nanoparticles (ZnO NPs) were ultrasonically spray-coated on commercial-grade polyethylene terephthalate (PET) and poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) films. The most suitable parameters for the ink composition, the ultrasonic spray-coating process, and the number of coating passes (up to 50x) were selected on the basis of a series of experiments. The oxygen gas barrier properties in terms of the oxygen transmission rate (OTR) of neat PET, and 3x, 5x, 10x, and 50x ZnO NP-coated PET and PHBHHx substrates were investigated. The OTR values for neat PET, and 3x, 5x, and 10x ZnO NP-coated PET substrates were found to be the same; however, a 5% reduction in OTR for 50x ZnO NP-coated PET substrate was observed compared to the neat PET substrate. No reduction in OTR was found for any above number of coating passes on PHBHHx substrates against the neat PHBHHx substrate. However, the ultraviolet (UV) tests of 3x, 5x, and 10x ZnO NP-coated PET and PHBHHx substrates revealed a significant decrease in percentage transmission for 10x coated PET and PHBHHx substrates as compared to their 3x and 5x ZnO NP-coated substrates, respectively. It was revealed from the study that the 50x ZnO NP coating of the PET substrate created a slight difference in OTR as compared to the reference substrate. However, the ultrasonic spray-coating method created a significant UV barrier effect for 3x, 5x, and 10x ZnO NP-coated PET and PHBHHx substrates, which demonstrates that the optimized coating method cannot be used to create a high oxygen barrier but can certainly be applied for UV barrier applications in food packaging. It is concluded that ultrasonic spray deposition of ZnO NPs on PET and PHBHHx materials has shown promising results for UV barrier properties, demonstrating the advantages of using this method compared to other coating methods with regard to cost-effectiveness, precise coating, and better process control.