Interfacial Metal Chlorides as a Tool to Enhance Charge Carrier Dynamics, Electroluminescence, and Overall Efficiency of Organic Optoelectronic Devices

Abstract

Interface engineering is the key to optimizing optoelectronic device performance, addressing challenges like reducing potential barriers, passivating interface traps, and controlling recombination of charges. Metal fluorides such as lithium fluoride are employed in interface modification within organic devices due to their strong dipole characteristics but carry health risks, high processing costs, and minimal impact on interface traps in organic electronics. Hence, this study investigates alternative metal chloride (MC) nanocrystals (sodium, cesium, rubidium, and potassium chlorides) that exhibit a strong dipole moment and are readily processable with the aim of reducing the influence of interface traps. Interfacial properties are assessed via various techniques, including electron paramagnetic resonance, X-ray/ultraviolet photoelectron spectroscopy, capacitance-voltage measurements, and density functional theory calculations. In organic light-emitting diodes (OLEDs), the influence of MC on charge transfer, trap density, and light emission properties is evaluated. MCs in ZnO:PEIE nanocomposites (NCs) show improved charge transport, accelerated trapping/detrapping in ZnO:PEIE NCs, and a 50% reduction in active traps in NaCl-based devices versus the reference without MCs. RbCl-, CsCl-, and NaCl-based OLEDs exhibit substantial reductions in the potential barrier between the electron injection layer and the metal contact (Al) from 4.43 to 2.93, 3.02, and 4 eV, respectively, accompanied by enhancements of 35, 27, and 25% in electroluminescence intensity.